We will need to look at this with some care to sort out the patterns and reasons. In the Hinsberg test, an amine is reacted with benzene sulfonyl chloride. The hydrocarbon chains have to force their way between water molecules, breaking hydrogen bonds between water molecules. . Both molecules contain the same number of electrons and have, as near as makes no difference, the same shape. Some slightly positive hydrogen atoms won't be able to find a lone pair to hydrogen bond with. Where there might be confusion about where the -NH2 group is attached to a chain, the simplest way of naming the compound is to use the "amino" form. It is useful to compare the boiling point of methylamine, CH3NH2, with that of ethane, CH3CH3. Let’s look at what are called carbons that are bonded to other atoms and atomic groups such as halides, hydroxides, amines. An example of this type of reaction is given below. The chlorination of benzene sulfonic acid or the salts of benzene sulfonic acid with phosphorus oxychloride (POCl3) gives the required reagent. In primary amines, only one of the hydrogen atoms in the ammonia molecule has been replaced. A carbon is called primary if it has only one neighboring alkyl carbon atom, secondary if it has two and tertiary for three linked alkyl carbon atoms. In the Hinsberg Test Let’s go back to the carbons. 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